Carbon Tetrachloride having actually its chemical formula together CCl4 is an organic compound. It is a colorless liquid with a sweet smell. That is also toxic to the human body on its straight exposure. Us will study the nature of CCl4 in detail. Chemistry students may have actually doubts about whether CCl4 is polar or nonpolar. So, In this article, I will answer this question and will cover the bordering topics too.

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SO, Is CCl4 polar or nonpolar? CCl4 (Carbon tetrachloride) is nonpolar in nature. Back the 4 bonds C-Cl room polar because of the difference in electronegativity that Chlorine(3.16) and also Carbon(2.55), CCl4 is nonpolar because the shortcut polarity it s okay canceled v each other because of the symmetrical geometrical structure (tetrahedral) that the CCl4 molecule.

Carbon Tetrachloride is one IUPAC name provided to CCl4 and it exists together a fluid state at room temperature. That produces a sweet odor that have the right to be conveniently detected at lower levels.

It was found by Henri Victor Regnault in the year 1839.

CCl4 molecule has actually one carbon atoms attached to the four chlorine atom. All four bond C-Cl are comparable as well as symmetrical to every other.

It is crucial to recognize that the opposite of a chemical compound is a very important variable in identify the polarity the a compound.

It can be understood since Carbon and Chlorine atom have a various value of electronegativity in other words (C= 2.55, Cl= 3.16). Do the C-CL link a polar covalent bond.

Therefore all 4 C-Cl bonds have actually a dipole moment value together well. Yet due come the the contrary of all four bonds, the dipole moment of the C-Cl bond gets canceled by opposing C-Cl bond. As a result, the network dipole moment turns out to be zero make the CCl4 a nonpolar molecule.

Methane gas (CH4) does likewise has the very same structure as CCl4.

What are Polar and Nonpolar Molecules?

It is to be provided that a molecule is taken into consideration to be polar if the network dipole moment of that molecule is zero. However, the is feasible to have the visibility of a polar bond within a nonpolar molecule.

As discussed over in CCl4, C-CL has some value of dipole moment and also is polar in nature but in its entirety CCl4 molecule is nonpolar in nature because the network dipole moment of CCl4 molecule is zero.

Polar molecule: These space the molecule that have some confident value of net dipole moment. These molecules also have asymmetric geometrical structures. A chemistry bond is claimed to it is in polar if the charges room not equally distributed over both atoms creating that bond. The electrons are not same shared among both atoms.

In together chemical bonds, the electron pair gets slightly propelled towards the much more electronegative atom among both atoms. Because of the distinction in electronegativity and also asymmetric geometry, this molecule i do not care polar.

Non-Polar molecules: The molecules that have actually net dipole minute as zero is a nonpolar molecule. In this molecules, the geometrical framework is additionally symmetric.

Among 2 atoms creating a chemistry bond, the bond is said to it is in polar if the charges room equally dispersed over both of castle that way the electrons space equally common by both of the atoms.

Why CCl4 is Nonpolar?

The CCl4 is nonpolar in nature due to the fact that of the symmetrical tetrahedral geometrical structure. Although the C-CL shortcut is polar in nature as Carbon and Chlorine atoms have a difference in your electronegativity.

As a result, the C-Cl bond also has a dipole moment. But due to symmetry structure, the net dipole minute gets canceled through each other forming CCl4 (Carbon Tetrachloride) a nonpolar molecule.

The polarity the a molecule counts upon the various factors questioned below.

Factors influence polarity of a compound

Electronegativity: in a chemistry bond in between two atoms, the link is stated to be polar if the 2 atoms have actually a distinction in your electronegativity. Higher the difference of electronegativity of 2 atoms an ext is the polarity of that bond.

But the is very important to know that molecule having actually polar bond within itself can also be nonpolar due to the fact that of its symmetrical structure. In together cases, the polarity of bond canceled out through each other.

Geometrical Structure: The molecule having its symmetrical geometrical shape is nonpolar in nature. The network dipole moment value turns out to it is in zero for symmetrical molecules.

Dipole moment: The molecules having actually net dipole minute are polar in nature vice versa, the molecules that have zero dipole minute are nonpolar in nature.

Geometrical framework of CCl4

If we talk around the geometrical structure of tetrachloromethane, the 4 bonds C-Cl lie at symmetric orientations relative to various other C-Cl bonds. The carbon atom is the main atom connected with four C-Cl bonds.

The carbon atom has four electrons in that outermost shell and also all 4 bonds take part in the formation of covalent bonds created with 4 chlorine atoms leaving behind no lone pair on the carbon atom.

The CCl4 forms the tetrahedral geometry and also the bond angle in the CCl4 molecule is about 109.5 degrees.

Carbon tetrachloride develops sp3 hybridization through one s orbital and three p orbitals of Carbon.

All the non-bonding electrons in CCl4 tends to develop a repulsive force among each other causing the bond edge of 109.5 degrees with each other and resulting in a tetrahedral shape.

For detailed information around valence electrons and also the lewis structure, you must go through the lewis structure, hybridization of CCl4.


Synthesis the CCl4

The formation of tetrachloromethane is done in the year 1839 by the French chemist Henri Victor Regnault. It to be synthesized by reaction chloroform and also chlorine.

But nowadays, the process of manufacturing tetrachloromethane is excellent by dealing with methane v chlorine. The reaction is provided as below

CH4 (Methane) + 4Cl2 (chlorine) ———> CCl4 + 4 HCl (acid)

Before the 1950s, the process of manufacturing carbon tetrachloride to be done by treating carbon disulfide with chlorine at 105 to 130 levels Celcius.

CS2 (carbon disulphide) + 3Cl2 (Chlorine) ——-> CCl4 + S2Cl2

Physical and also Chemical properties of CCl4

CCl4 (Carbon Tetrachloride) exists as a liquid at room temperature.It exists as a colorless liquid and also gives a sweet smell.The melting allude of Carbon Tetrachloride is about -23 degrees Celcius.It has actually its boiling point around 76 levels Celcius.The geometrical shape of Carbon Tetrachloride is symmetrical tetrahedral.The thickness of Carbon Tetrachloride is about 1.5867 g cm−3.CCl4 is soluble in chloroform, formic acid, alcohol, ether, CS2, naphtha, benzene.The vapor pressure of CCl4 is 11.94 kPa in ~ 20 °C.CCl4 is toxicity in nature and it has ozone-depleting properties and likewise classified as a greenhouse gas.

Uses that CCl4

The Tetra Chloromethane becomes wonderful solvent for countless nonpolar substances since of that nonpolar nature.It is a great source that chlorine for the synthetic of chlorine-based organic compounds.It additionally has its good use in NMR spectroscopy as result of the absence of hydrogen atom in the CCl4 molecule.Tetrachloromethane has actually its great use in the fire extinguishers, it prevents the fire by extinguishing the flames that fire.


The molecule of CCl4 is nonpolar in nature because of its symmetrical tetrahedral structure. Yet the C-Cl shortcut is a polar covalent bond, however the 4 bonds publication the polarity the each other and kind a nonpolar CCl4 molecule.

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So, In this article, i tried come cover the nonpolar nature that Carbon Tetrachloride molecule(CCl4). If you men have any kind of questions concerning this, you have the right to ask that in the comment ar below. We will certainly reach out to you as shortly as possible.