|630 g/l (20 °C)|
|UN3087 5.1+6.1/PG III|
SECTION 1. IDENTIFICATION
Product Name: Barium Nitrite
Product Number: every applicable American facets product codes, e.g. BA-NIT-01-C.AHYD
CAS #: 13465-94-6
Relevant figured out uses of the substance: clinical research and also development
Emergency telephone number:Domestic, phibìc America: +1 800-424-9300International: +1 703-527-3887
SECTION 2. Dangers IDENTIFICATION
Classification the the problem or mixture in accordance through 29 CFR 1910 (OSHA HCS)GHS03 Flame over circleOx. Sol. 3 H272 may intensify fire; oxidizer.GHS07Acute Tox. 4 H302 Harmful if swallowed.Acute Tox. 4 H332 Harmful if inhaled.Hazards not otherwise classified No data availableGHS brand elements, consisting of precautionary statements
Hazard pictogramsGHS03 GHS07Signal indigenous WarningHazard statementsH272 might intensify fire; oxidizer.H302+H332 Harmful if swallowed or if inhaled.Precautionary statementsP221 Take any type of precaution to protect against mixing v combustibles.P210 store away indigenous heat/sparks/open flames/hot surfaces. No smoking.P220 Keep/Store far from clothing/combustible materials.P261 stop breathing dust/fume/gas/mist/vapors/spray.P304+P340 IF INHALED: Remove human to new air and keep comfortable for breathing.P501 Dispose that contents/container in accordance with local/regional/national/international regulations.WHMIS classificationC - Oxidizing materialsD1B - toxicity material resulting in immediate and serious toxicity effectsClassification systemHMIS ratings (scale 0-4)(Hazardous materials Identification System)HEALTHFIREREACTIVITY201Health (acute effects) = 2Flammability = 0Physical risk = 1Other hazardsResults that PBT and vPvB assessmentPBT: N/AvPvB: N/A
SECTION 3. COMPOSITION/INFORMATION ~ above INGREDIENTS
SubstancesCAS No. / substance Name:13465-94-6 Barium nitriteIdentification number(s):EC number: 236-709-9Index number: 056-002-00-7
SECTION 4. Very first AID MEASURES
Description of very first aid measuresIf inhaled:Supply patient with fresh air. If not breathing, administer artificial respiration. Keep patient warm.Seek prompt medical advice.In situation of skin contact:Immediately wash through soap and water; wash thoroughly.Seek instant medical advice.In instance of eye contact:Rinse opened eye for number of minutes under running water. Above a physician.If swallowed:Seek clinical treatment.Information because that doctorMost necessary symptoms and also effects, both acute and also delayed:No data availableIndication of any kind of immediate medical attention and special treatment needed:No data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing mediaSuitable extinguishing agents Product is no flammable. Usage fire-fighting measures that suit the neighboring fire.For safety factors unsuitable extinguishing agents Halocarbon extinguisherSpecial hazards emerging from the substance or mixtureThis substance is one oxidizer and also its heat of reaction through reducing agents or combustibles may reason ignition.If this product is connected in a fire, the adhering to can it is in released:Nitrogen oxides (NOx)Barium oxideAdvice for firefightersProtective equipment:Wear self-contained respirator.Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL relax MEASURES
Personal precautions, protective equipment and also emergency proceduresUse an individual protective equipment. Keep unprotected people away.Ensure sufficient ventilationEnvironmental precautions: carry out not permit material come be exit to the setting without main permits.Methods and materials for containment and cleanup:Dispose that contaminated material as waste follow to section 13.Ensure sufficient ventilation.Prevention of second hazards:Acts as an oxidizing certified dealer on organic materials such together wood, document and fatsKeep away from combustible material.Reference to various other sectionsSee ar 7 for info on for sure handlingSee ar 8 for info on an individual protection equipment.See ar 13 because that disposal information.
SECTION 7. HANDLING and STORAGE
HandlingPrecautions for for sure handlingKeep container tightly sealed.Store in cool, dry ar in tightly closeup of the door containers.Ensure great ventilation in ~ the workplace.Information around protection versus explosions and fires:Substance/product can reduce the ignition temperature the flammable substances.This substance is an oxidizer and its warm of reaction with reducing agents or combustibles may cause ignition.Conditions for for sure storage, including any kind of incompatibilitiesRequirements to be met by storerooms and receptacles: No special requirements.Information around storage in one common storage facility:Store far from flammable substances.Store away from reducing agents.Do not keep with essential materials.Store away from steel powders.Further information about storage conditions:Keep container strictly sealed.Store in cool, dry conditions in well-sealed containers.Specific finish use(s) No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technological systems:Properly operating chemical fume hood designed for hazardous chemicals and having an average confront velocity of at least 100 feet every minute.Control parametersComponents v limit values that call for monitoring in ~ the workplace:Barium, and also soluble compounds, together Bamg/m3ACGIH TLV 0.5; no classified as a human being carcinogenAustria MAK 0.5Belgium TWA 0.5Denmark TWA 0.5Finland TWA 0.5Germany MAK 0.5 (total dust)Hungary 0.5-STELIreland TWA 0.5Korea TLV 0.5Netherlands MAC-TGG 0.5Norway TWA 0.5Poland TWA 0.5; 1.5-STELSweden TWA 0.5Switzerland MAK-W 0.5United Kingdom LTEL 0.5USA PEL 0.5Additional information: No dataExposure controlsPersonal security equipmentFollow common protective and hygienic techniques for taking care of chemicals.Keep far from foodstuffs, beverages and also feed.Remove every soiled and contaminated garments immediately.Wash hands prior to breaks and at the end of work.Maintain an ergonomically appropriate working environment.Breathing equipment: Use perfect respirator as soon as high concentrations are present.Protection that hands:Impervious glovesInspect gloves before use.The an option of suitable gloves not just depends top top the material, but likewise on quality. High quality will vary from manufacturer to manufacturer.Penetration time the glove material (in minutes) No data availableEye protection: security glassesBody protection: Protective job-related clothing.
SECTION 9. PHYSICAL and also CHEMICAL PROPERTIES
Information on straightforward physical and also chemical propertiesAppearance:Form: CrystallineColor: WhiteOdor: WeakOdor threshold: No data available.pH: N/AMelting point/Melting range: 115 °C (239 °F) (dec)Boiling point/Boiling range: No data availableSublimation temperature / start: No data availableFlash point: N/AFlammability (solid, gas) contact with combustible material may cause fire.Ignition temperature: No data availableDecomposition temperature: No data availableAutoignition: No data available.Danger of explosion: No data available.Explosion limits:Lower: No data availableUpper: No data availableVapor pressure: N/ADensity in ~ 20 °C (68 °F): 3.173 g/cm3 (26.479 lbs/gal)Relative thickness No data available.Vapor thickness N/AEvaporation rate N/ASolubility in / Miscibility withWater at 20 °C (68 °F): 630 g/lPartition coefficient (n-octanol/water): No data available.Viscosity:Dynamic: N/AKinematic: N/AOther details No data available
SECTION 10. STABILITY and also REACTIVITY
Reactivity may intensify fire; oxidizer.Chemical security Stable under recommended warehouse conditions.Thermal decomposition / problems to be avoided: Decomposition will not happen if used and also stored follow to specifications.Possibility that hazardous reactionsReacts with reducing agentsReacts with flammable substancesConditions to stop No data availableIncompatible materials:AminesCyanidesFlammable substancesReducing agentsOrganic materialsMetal powdersHazardous decomposition products:Nitrogen oxides
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effectsAcute toxicity:Harmful if inhaled.Harmful if swallowed.LD/LC50 values that are pertinent for classification: No dataSkin irritation or corrosion: Irritant come skin and also mucous membranes.Eye wake up or corrosion: Irritating effect.Sensitization: No sensitizing results known.Germ cell mutagenicity: No effects known.Carcinogenicity:EPA-D: no classifiable regarding human carcinogenicity: inadequate human and also animal evidence of carcinogenicity or no data are available.EPA-NL: Not most likely to it is in carcinogenic come humans.ACGIH A4: no classifiable as a human carcinogen: insufficient data ~ above which to classify the agent in terms of its carcinogenicity in human beings and/or animals.Reproductive toxicity: No results known.Specific target organ mechanism toxicity - repetitive exposure: No impacts known.Specific target organ device toxicity - single exposure: No effects known.Aspiration hazard: No effects known.Subacute to chronic toxicity:Barium compound may cause severe gastroenteritis, including abdominal pain, vomiting and also diarrhea, tremors, faintness, paralysis of the arms and also legs, and slowor rarely often, rarely heartbeat. Severe instances may develop collapse and also death due to respiratory failure. Dissolve barium link are much more likely to cause these effectsthan insoluble compounds. Inhalation that fumes may reason sore throat, coughing, labored breathing, and irritation the the respiratory tract tract as well as the abovesymptoms.Subacute to chronic toxicity: No impacts known.Subacute come chronic toxicity:Exposure to nitrites may reason nausea, vomiting, cyanosis, and also collapse right into a coma. Small doses cause a autumn in blood pressure, rapid pulse, muscle weakness,headache and visual disturbances.Additional toxicological information: to the finest of our knowledge the acute and also chronic toxicity that this substance is not totally known.
SECTION 12. Ecological INFORMATION
ToxicityAquatic toxicity: No data availablePersistence and also degradability No data availableBioaccumulative potential No data availableMobility in floor No data availableAdditional eco-friendly information:Do not permit material come be exit to the atmosphere without main permits.Do not permit undiluted product or huge quantities to reach groundwater, water courses, or sewer systems.Avoid transfer into the environment.Results of PBT and also vPvB assessmentPBT: N/AvPvB: N/AOther adverse effects No data available
SECTION 13. Handle CONSIDERATIONS
Waste treatment methodsRecommendation Consult official regulations come ensure ideal disposal.Uncleaned packagings:Recommendation: Disposal should be made according to official regulations.
SECTION 14. Transfer INFORMATION
UN-NumberDOT, IMDG, IATA UN3087UN suitable shipping nameDOT Oxidizing solid, toxic, n.o.s. (barium nitrite)IMDG, IATA OXIDIZING SOLID, TOXIC, N.O.S. (barium nitrite)Transport peril class(es)DOTClass 5.1 Oxidising substances.Label 54.1+6.1Class 5.1 (OT2) Oxidizing substancesLabel 5.1+6.1IMDG, IATAClass 5.1 Oxidising substances.Label 5.1+6.1Packing groupDOT, IMDG, IATA IIIEnvironmental hazards: N/ASpecial precautions because that user Warning: Oxidizing substancesTransport in mass according to Annex II of MARPOL73/78 and also the IBC password N/ATransport/Additional information:DOTMarine Pollutant (DOT): NoItem:UN "Model Regulation": UN3087, Oxidizing solid, toxic, n.o.s. (barium nitrite), 5.1 (6.1), III
SECTION 15. Regulatory INFORMATION
Safety, health and also environmental regulations/legislation certain for the substance or mixtureGHS label elements, including precautionary statementsHazard pictogramsGHS03 GHS07Signal indigenous WarningHazard statementsH272 might intensify fire; oxidizer.H302+H332 Harmful if swallowed or if inhaled.Precautionary statementsP221 Take any precaution to protect against mixing with combustibles.P210 keep away from heat/sparks/open flames/hot surfaces. No smoking.P220 Keep/Store far from clothing/combustible materials.P261 avoid breathing dust/fume/gas/mist/vapors/spray.P304+P340 IF INHALED: Remove human to fresh air and keep comfortable for breathing.P501 Dispose the contents/container in accordance through local/regional/national/international regulations.National regulationsAll materials of this product are listed in the U.S. Environmental Protection firm Toxic Substances manage Act chemical substance Inventory.All components of this product are detailed on the Canadian Non-Domestic Substances perform (NDSL).SARA ar 313 (specific toxicity chemical listings)7787-38-4 Barium nitriteCalifornia Proposition 65Prop 65 - Chemicals recognized to reason cancer substance is no listed.Prop 65 - Developmental toxicity problem is not listed.Prop 65 - Developmental toxicity, female problem is not listed.Prop 65 - Developmental toxicity, male Substance is no listed.Information about limitation of use:For use only by technically default individuals.This product consists of barium and also is subject to the reporting requirements of ar 313 the the Emergency Planning and Community ideal to recognize Act the 1986 and40CFR372.Other regulations, limitations and also prohibitive regulationsSubstance of really High issue (SVHC) according to the reach Regulations (EC) No. 1907/2006. Problem is not listed.The problems of constraints according to write-up 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) because that the manufacturing, placing on themarket and use need to be observed.Substance is no listed.Annex XIV the the reach Regulations (requiring Authorisation for use) problem is no listed.Chemical security assessment: A Chemical safety Assessment has actually not been brought out.SECTION 16. Other INFORMATION